My Slaves to Darkness army, the Brotherhood of Strife, is a twisted knightly order centered around two warriors exiled from a Free City for letting their sibling rivalry endanger a battle's success. The knights and their followers have since turned to competing for the favor of the Chaos Gods, but maintain a strict discipline in battle that comes from their profaned knightly code. They lair in the realm of Ulgu, and specialize in lightning strikes and misdirection to beguile their foes and sow discord between other factions.
The leader of the faction is Kurath, the elder of the two Brothers of Strife, while his brother Lothran is his second in command, and the sorcerer Xyrados the Willbreaker serves as their vizier and enforcer from the back of an enslaved manticore. The tests of lesser warriors hoping to join the Brotherhood or ascend to the ranks of the Chaos Knights are overseen by the Chaos Lord Murazed, the Master of Trials. Finally, two more sorcerers, Siriak the Darkseeker and Kirias the Light-twister, work with the Brotherhood to plumb Ulgu's mysteries. No one is sure exactly what the relationship between these last two is, or if they are even two separate beings at all instead of the result of a particularly strange mutation. In rules terms, all those characters are my heroes--two Karkadrak Lords, and a Manticore-riding Sorcerer for leaders, then on foot Chaos Lords and Sorcerer Lords backing them up.
When I get around second army, I'm debating between an Ossiarch force scavenging for ancient and potent remains in Ghyran called the Gnarlbone Legion or some kind of Lumineth force (more details pending). I had a neat idea for a Ossiarch army made entirely from the bones of sorcerers and chaos followers that would serve as a sign of Nagash's arrogance and dominion over the dead, but I couldn't make the list work, sadly.